A shot of the St. Louis skyline from across the big muddy.
Adjustments:
Straighten
crop
healing brush to remove power lines etc.
levels layer
Deep Blue filter layer at 36%
Shadows and Highlights
Briliance and Warmth Filter
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I like the sun rays, but might be a bit too much to look at here with the arch included in the skyline. Maybe a slightly different angle would work better.