Might I be so bold as to ask where the actual sun was in the photo? I know you say midday, but how direct of sunlight were you getting and what was the azimuth and inclination? We'll assume the direction the camera is facing is the 0 degree mark for simplicity's sake.
Background exposure looks great. Question: Doesn't look like you defused the flashes, has a little harshness to it. Would a small soft box or umbrella help? I think I've seen it both ways.
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